homepage  Research  Publications  2014
 
X. M. Ni, X. S. Wang, S. G. Zhang and M. Zhao (2014) Journal Of Fire Sciences 32 417-430.
Date: 2015-03-29   Author: SKLFS  ,   Source: SKLFS  ,
 

X. M. Ni, X. S. Wang, S. G. Zhang and M. Zhao (2014) Experimental study on the performance of transition metal ions modified zeolite particles in suppressing methane/air coflowing flame on cup burner. Journal/Journal Of Fire Sciences 32 417-430. [In English]
Web link: http://dx.doi.org/10.1177/0734904114529402
Keywords: ,Zeolite, metal ions, cup-burner, fire suppression, flame, DIFFUSION FLAMES, FIRE SUPPRESSION, INHIBITION, SALTS, EXTINGUISHMENT, MECHANISMS, ADDITIVES, HYDROXIDE, AEROSOLS, WATER

Abstract: This study investigated the performance of three kinds of transition metal ions (Mn2+, Cu2+, and Zn2+) modified zeolite 4A particles in suppressing methane/air coflowing flames on cup burner. Ion-exchange method was employed to incorporate different amount of transition metal ions into parent zeolite 4A. Fire suppression effectiveness of zeolites containing varied molar percentage of metal ions was tested by cup-burner method. Results showed that transition metal ions modified zeolites outperformed the parent zeolite 4A with a ranking order of Mn2+ >, Cu2+ >, Zn2+. Performance of the zeolite particles was affected by the percentage of transition ions loaded, which dominated the number of active sites and Brunauer-Emmett-Teller surface area of the particles. Increasing molar percentage of metal ions loading increased the capacity to scavenge flame radicals, but decreased Brunauer-Emmett-Teller surface area of the particles. There existed an optimized molar percentage of transition metal ions loading where the best fire-suppressing effectiveness was exhibited.

 
Print    Close
 
 
   
  
 
Relevant link
Contact us
State Key Laboratory of Fire Science, University of Science and Technology of China
Jinzhai Road 96, Hefei, Anhui, P. R. China
P. O.: 230026
   
Tel:(+86)551 63601651
Fax:(+86)551 63601669
E-mail:sklfs@ustc.edu.cn
 
 
Copyright © 1990-2011 State Key Laboratory of Fire Science, University of Science and Technology of China
Tel:(+86)551 3601651 | Fax:(+86)551 3601669 | E-mail:sklfs@ustc.edu.cn | ICP: D20380176