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X. M. Ni, Z. Zheng, X. S. Wang, S. G. Zhang and M. Zhao (2014) Journal Of Alloys And Compounds 592 135-139.
Date: 2015-03-29   Author: SKLFS  ,   Source: SKLFS  ,
 

X. M. Ni, Z. Zheng, X. S. Wang, S. G. Zhang and M. Zhao (2014) Fabrication of hierarchical zeolite 4A microspheres with improved adsorption capacity to bromofluoropropene and their fire suppression performance. Journal/Journal Of Alloys And Compounds 592 135-139. [In English]
Web link: http://dx.doi.org/10.1016/j.jallcom.2013.12.025
Keywords: ,Nanostructured materials, Zeolite, Mixed solvents, Chemical synthesis, Adsorption, CALCIUM-CARBONATE, KAOLIN, MECHANISM, ETHANOL, SODIUM, ZSM-5, NAA

Abstract: Novel hierarchical zeolite 4A microspheres consisted of interconnected nanoflakes were successfully prepared from Kaolin precursor in a simple ethanol-water mixed solvent system. While in aqueous solution without ethanol, only commonly cubic particles were obtained. It was found that the concentration of ethanol in the solvent was crucial to the production of microspheres. There existed an optimized concentration range of ethanol where microspheres were fabricated with highly yield. Thus-prepared single-phase zeolite 4A microspheres exhibited a large Brunauer-Emmett-Teller (BET) surface area of 666.9 m(2)/g, pore volume of 0.0147 cm(3)/g and average pore size of 6.9 nm. The porous spheres exhibited an adsorption capacity of 8.7 wt.% to a clean gas fire suppressant of 2-bromo-3,3,3-trifluoropropene (BTP) at room temperature, much higher than that of conventional cubic zeolite 4A particles (4.2 wt.%). Bench scale fire tests revealed that these zeolite 4A microspheres soaked with BTP exhibited much better performance than that of cubic counterparts in suppressing methane/air coflowing diffusion flames in cup burner, with the fire extinguishing concentration decreased by more than 20% at the comparable powder discharging rate. Such an improvement could be ascribed to the larger surface area and higher adsorption capacity of zeolite 4A microspheres. (C) 2014 Published by Elsevier B.V.

 
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